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Advanced Level Organic Chemistry: INDEX of AROMATIC CHEMISTRY NOTES

Part 7. The chemistry of Aromatic Compounds

Doc Brown's Chemistry Advanced Level Pre-University Chemistry Revision Study Notes for UK KS5 A/AS GCE IB advanced level organic chemistry students US K12 grade 11 grade 12 organic chemistry the physical and chemical properties of aromatic compounds chemistry of benzene and methylbenzene

7.0 INDEX of all My Aromatic Chemistry Notes

7.1 Molecular structure and nomenclature of aromatic compounds

(7.1 includes an extensive introduction on how to write and display aromatic formulae including isomers - lots of examples)

7.2 Proof of the structure of benzene, aromaticity and an introduction to electrophilic substitution in arenes

7.3 Sources & synthesis of including alkylation (electrophilic substitution mechanism) and the physical properties of arenes (aromatic hydrocarbons) and use of arenes like benzene in fuels

7.4 Free radical addition reactions of benzene and methylbenzene with hydrogen (hydrogenation) and side-chain chlorination substitution of the methyl group of methylbenzene

7.5 Electrophilic substitution - ring nitration of benzene and methylbenzene, properties and uses of nitro-aromatics

7.6 Electrophilic substitution - ring halogenation of benzene & methylbenzene, properties & uses of aryl halides

7.7 Electrophilic substitution - ring sulfonation of arenes, properties & uses of alkylbenzenesulfonic acids

7.8 Electrophilic substitution - ring acylation of arenes, properties & uses of aromatic ketones & aromatic aldehydes

7.9 The physical and chemical properties of phenol and some of its derivatives and their uses

7.10 Physical & chemical properties of phenylamine, selected derivatives including diazonium ions and dyes

7.11 The physical and chemical properties of benzoic acid and selected derivatives

7.12 The structure, properties and uses of polyesters and polyamides involving aromatic monomers

7.13 Examples of aromatic compounds from the pharmaceutical industry and those found in natural products

7.14 Explaining the orientation of products of putting a 2nd substituent into a monosubstituted benzene derivative

(perhaps aspects of 7.14 go beyond what is normally required in pre-university chemistry courses?)

See also Part 15 Organic Chemistry Spectroscopy - examples of IR, mass, H-1 NMR and C-13 NMR spectra

and specific spectra of aromatic compounds

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The following notes below were written before the expanded notes listed above, but they do have basic reaction conditions, reagents and general equations as well as detailed notes on the mechanisms involved.

Nitration to give nitro-aromatics like nitrobenzene

Chlorination to chloro-aromatics like chlorobenzene

Alkylation to give alkyl-aromatics like methylbenzene [Friedel-Crafts reaction]

Acylation to give aromatic ketones [Friedel-Crafts reaction]

Sulfonation to give a sulfonic acid like benzenesulfonic acid

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* THE SPECTRA OF ORGANIC COMPOUNDS *

Infrared spectra of AROMATIC HYDROCARBONS

The infrared spectrum of Benzene

The infrared spectrum of Methylbenzene

The infrared spectrum of 1,2-dimethylbenzene

The infrared spectrum of 1,3-dimethylbenzene

The infrared spectrum of 1,4-dimethylbenzene

The infrared spectrum of Ethylbenzene

The infrared spectrum of Propylbenzene

The infrared spectrum of (1-methylethyl)benzene  /  2-phenylpropane (Cumene)

The infrared spectrum of 1,3,5-trimethylbenzene

The infrared spectrum of Chlorobenzene

The infrared spectrum of phenol

The infrared spectrum of benzaldehyde

The infrared spectrum of benzoic acid

Mass spectra of AROMATIC HYDROCARBONS

The mass spectrum of Benzene

The mass spectrum of Methylbenzene

The mass spectrum of 1,2-dimethylbenzene

The mass spectrum of 1,3-dimethylbenzene

The mass spectrum of 1,4-dimethylbenzene

The mass spectrum of Ethylbenzene

The mass spectrum of Propylbenzene

The mass spectrum of (1-methylethyl)benzene  /  2-phenylpropane (Cumene)

The mass spectrum of 1,3,5-trimethylbenzene

The mass spectrum of Chlorobenzene

The mass spectrum of phenol

The mass spectrum of benzaldehyde

The mass spectrum of benzoic acid

H-1 NMR spectra of AROMATIC HYDROCARBONS

The H-1 NMR spectrum of Benzene

The H-1 NMR spectrum of Methylbenzene

The H-1 NMR spectrum of 1,2-dimethylbenzene

The H-1 NMR spectrum of 1,3-dimethylbenzene

The H-1 NMR spectrum of 1,4-dimethylbenzene

The H-1 NMR spectrum of Ethylbenzene

The H-1 NMR spectrum of Propylbenzene

The H-1 NMR spectrum of (1-methylethyl)benzene  /  2-phenylpropane (Cumene)

The H-1 NMR spectrum of 1,3,5-trimethylbenzene

The H-1 NMR spectrum of Chlorobenzene

The H-1 NMR spectrum of phenol

The H-1 NMR spectrum of Benzaldehyde

The H-1 NMR spectrum of benzoic acid

C-13 NMR spectra of AROMATIC HYDROCARBONS

The C-13 NMR spectrum of Benzene

The C-13 NMR spectrum of Methylbenzene

The C-13 NMR spectrum of 1,2-dimethylbenzene

The C-13 NMR spectrum of 1,3-dimethylbenzene

The C-13 NMR spectrum of 1,4-dimethylbenzene

The C-13 NMR spectrum of Ethylbenzene

TheC-13 NMR spectrum of Propylbenzene

The C-13 NMR spectrum of (1-methylethyl)benzene  /  2-phenylpropane (Cumene)

The C-13 NMR spectrum of 1,3,5-trimethylbenzene

The C-13 NMR spectrum of Chlorobenzene

The C-13 NMR spectrum of phenol

The C-13 NMR spectrum of Benzaldehyde

The C-13 NMR spectrum of benzoic acid


All Advanced A Level Organic Chemistry Notes

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Doc Brown's Advanced Level Chemistry Revision Notes

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 All Advanced Organic Chemistry Notes

 

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