Advanced Organic Chemistry: Mass spectrum of chlorobenzene
The mass spectrum of chlorobenzene
Doc Brown's Chemistry Advanced Level Pre-University Chemistry Revision Study Notes for UK IB KS5 A/AS GCE advanced A level organic chemistry students US K12 grade 11 grade 12 organic chemistry courses involving molecular spectroscopy analysing mass spectra of chlorobenzene
Interpreting the fragmentation pattern of the mass spectrum of chlorobenzene
[M]+ are the molecular ion peaks with an m/z of 112 and 114 corresponding to [C6H535Cl]+ AND [C6H535Cl]+ the original chlorobenzene molecule minus an electron, [C6H5Cl]+.
The small M+1 peaks at m/z 113 and 115, corresponds to an ionised chlorobenzene molecule with one 13C atom in it i.e. an ionised chlorobenzene molecule of formula 13C12C5H5Cl.
Identifying the species giving the most prominent peaks (apart from M) in the fragmentation pattern of chlorobenzene.
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