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Part 4.
The chemistry of ALCOHOLS (and a mention of isomeric ethers) -
INDEX of all revision notes on the
chemistry of alcohols
Doc Brown's
Chemistry Advanced Level Pre-University Chemistry Revision Study Notes for UK
KS5 A/AS GCE IB advanced level organic chemistry students US K12 grade 11 grade 12 organic chemistry
physical and chemical properties of alcohols principal reactions of
aliphatic alcohols
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Chemistry Revision Notes
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INDEX of all revision notes
on the chemistry of alcohols
(plus a few notes on ethers which
are isomeric with alcohols)
4.1
Molecular Structure and Nomenclature of
ALCOHOLS (and some ethers)
(Also includes an introduction as to how
to write and display alcohol and ether formulae including isomers)
Multiple choice quiz on naming alcohols and ethers
Type in name
(short answer) quiz on alcohols and ethers
To doc b! D o
mixed naming quiz 3rd, and 4th version by adding other structure/reaction Qs from
a 3rd data base?
4.2
The laboratory synthesis and
industrial manufacture of
alcohols
4.3
Physical properties
(boiling points, solubility) and intermolecular forces (including
isomeric ethers)
4.4
Combustion of alcohols,
enthalpies of combustion and use as fuels (plus a note on isomeric
ethers)
4.5
Controlled oxidation
of alcohols with selected oxidising
agents
4.6A
Important reactions with: metallic sodium, acid
chlorides and carboxylic acids to give esters
4.6B
Dehydration of alcohols to yield alkenes
4.7
Halogenation with hydrogen halides: Conversion of
alcohols to
halogenoalkanes
4.8
Chemical tests for alcohols
4.9
Examples of uses
of alcohols and occurrence in biological molecules -
biochemistry
See also Part 15
Organic Chemistry Spectroscopy - examples of IR, mass, H-1 NMR and C-13 NMR
spectra
Alcohol reaction
mechanisms
The following notes have
basic reaction conditions, reagents and general equations as well as
detailed notes on the mechanisms indicated
(overlap because they were written before above sections 4.2 to 4.8 were
compiled)
Conversion of an alcohol to a halogenoalkane
mechanism
Elimination of water from an
alcohol to give an alkene [acid catalysed, E1 and E2 mechanisms]
Esterification of acid
chlorides with alcohols
to give an ester mechanism
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THE SPECTRA OF ORGANIC
COMPOUNDS |
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Infrared spectra of ALCOHOLS
(see below for isomeric ethers apart from methanol)
The infrared spectrum of methanol
The infrared spectrum of Ethanol (ethyl alcohol)
The infrared spectrum of Propan-1-ol (1-propanol,)
The infrared
spectrum of Propan-2-ol (2-propanol)
Infrared spectra of 4
isomeric alcohols, molecular formula C4H10O
The infrared
spectrum of butan-1-ol (1-butanol)
The infrared spectrum of butan-2-ol (sec-butyl
alcohol)
The infrared
spectrum of 2-methylpropan-1-ol
The infrared
spectrum of 2-methylpropan-2-ol
Infrared spectra of ethers
The
infrared spectrum of methoxymethane (dimethyl ether)
(see isomeric ethanol)
The
infrared spectrum of methoxyethane
(see 2 isomeric alcohols C3H8O)
Infrared
spectra of 3 isomeric ethers, molecular formula
C4H10O
(see 4 isomeric alcohols too)
The infrared spectrum of
ethoxyethane (diethyl ether)
The
infrared spectrum of 1-methoxypropane (methyl propyl
ether)
The
infrared spectrum of 2-methoxypropane (methyl
isopropyl ether)
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Mass spectra of
ALCOHOLS
(see below for isomeric ethers apart from methanol)
The mass spectrum of methanol
The mass spectrum of Ethanol (ethyl alcohol)
The mass spectrum
of Propan-1-ol (1-propanol)
The mass spectrum
of Propan-2-ol (2-propanol)
Mass
spectra of 4 isomeric alcohols, molecular formula
C4H10O
The mass spectrum of butan-1-ol (1-butanol,)
The mass spectrum of butan-2-ol (sec-butyl alcohol)
The mass spectrum
of 2-methylpropan-1-ol
The mass spectrum
of 2-methylpropan-2-ol
Mass spectra of ethers
The mass
spectrum of methoxymethane (dimethyl ether)
(see isomeric ethanol)
The mass
spectrum of methoxyethane
(see 2 isomeric alcohols C3H8O)
Mass
spectra of 3 isomeric ethers, molecular formula
C4H10O
(see 4 isomeric alcohols too)
The mass spectrum of
ethoxyethane (diethyl ether)
The mass
spectrum of 1-methoxypropane (methyl propyl ether)
The mass
spectrum of 2-methoxypropane (methyl isopropyl ether)
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H-1 NMR spectra of
ALCOHOLS
(see below for isomeric ethers apart from methanol)
The H-1 NMR spectrum of
methanol
The H-1 NMR spectrum of
Ethanol (ethyl alcohol)
The H-1 NMR spectrum of
Propan-1-ol (1-propanol)
The H-1 NMR spectrum of
Propan-2-ol (2-propanol)
1H NMR spectra of 4
isomeric alcohols, molecular formula
C4H10O
The H-1 NMR
spectrum of butan-1-ol (1-butanol)
The H-1 spectrum of
butan-2-ol (sec-butyl alcohol)
The H-1 NMR
spectrum of 2-methylpropan-1-ol
The H-1 NMR
spectrum of 2-methylpropan-2-ol
H-1 proton NMR spectra of
ethers
The
H-1 NMR spectrum of methoxymethane (dimethyl ether)
(see isomeric ethanol)
The H-1
NMR spectrum of methoxyethane
(see 2 isomeric alcohols C3H8O)
1H NMR spectra of 3
isomeric ethers, molecular formula
C4H10O
(see 4 isomeric alcohols too)
The H-1 NMR spectrum of Ethoxyethane (diethyl ether)
The H-1
NMR spectrum of 1-methoxypropane (methyl propyl
ether)
The H-1
NMR spectrum of 2-methoxypropane (methyl isopropyl
ether)
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C-13 NMR
spectra of
ALCOHOLS
(see below for isomeric ethers apart from methanol)
The C-13 NMR spectrum of
methanol
The C-13 NMR spectrum Ethanol (ethyl alcohol)
The C-13 NMR spectrum of
Propan-1-ol (1-propanol)
The C-13 NMR spectrum of
Propan-2-ol (2-propanol)
C13 NMR spectra of 4
isomeric alcohols, molecular formula
C4H10O
The C-13 NMR spectrum of
butan-1-ol (1-butanol)
The C-13 NMR spectrum of
butan-2-ol
The C-13 NMR
spectrum of 2-methylpropan-1-ol
The C-13 NMR
spectrum of 2-methylpropan-2-ol
C-13 carbon-13 NMR
spectra of
ethers
The
C-13 NMR spectrum of methoxymethane (dimethyl ether)
(see isomeric ethanol)
The
C-13 NMR spectrum of methoxyethane
(see 2 isomeric alcohols C3H8O)
C13 NMR
spectra of 3 isomeric ethers, molecular formula
C4H10O
(see 4 isomeric alcohols too)
The C-13 NMR spectrum
of ethoxyethane
The
C-13 NMR spectrum of 1-methoxypropane (methyl propyl
ether)
The
C-13 NMR spectrum of 2-methoxypropane (methyl
isopropyl ether)
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