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Advanced Organic Chemistry: Mass spectrum of methoxymethane
The mass spectrum of methoxymethane (dimethyl ether) Doc Brown's Chemistry Advanced Level Pre-University Chemistry Revision Study Notes for UK IB KS5 A/AS GCE advanced A level organic chemistry students US K12 grade 11 grade 12 organic chemistry courses involving molecular spectroscopy analysing mass spectra of methoxymethane
Methoxymethane (dimethyl ether)
Revision notes on the structure and naming (nomenclature) of aliphatic ALCOHOLS and ETHERS Interpreting the fragmentation pattern of the mass spectrum of methoxymethane [M]+ is the molecular ion peak (M) with an m/z of 46 corresponding to [C2H6O]+, the original methoxymethane molecule minus an electron, [CH3OCH3]+. The small M+1 peak at m/z 47, corresponds to an ionised methoxymethane molecule with one 13C atom in it i.e. an ionised methoxymethane molecule of formula [13C12CH6O]+
The most abundant ion of the molecule under mass spectrometry investigation (methoxymethane) is usually given an arbitrary abundance value of 100, called the base ion peak, and all other abundances ('intensities') are measured against it. Identifying the species giving the most prominent peaks (apart from M) in the fragmentation pattern of methoxymethane. Unless otherwise indicated, assume the carbon atoms in methoxymethane are the 12C isotope. Some of the possible positive ions, [molecular fragment]+, formed in the mass spectrometry of methoxymethane based on [CH3OCH3]+.
See also comparing the IR, mass, 1H NMR and 13C NMR spectra of isomers of C2H6O below.
Key words & phrases: C2H6O CH3OCH3 image diagram on how to interpret and explain the mass spectrum of methoxymethane m/z m/e base peaks, image and diagram of the mass spectrum of methoxymethane, details of the mass spectroscopy of methoxymethane, low and high resolution mass spectrum of methoxymethane, prominent m/z peaks in the mass spectrum of methoxymethane, comparative mass spectra of methoxymethane, the molecular ion peak in the mass spectrum of methoxymethane, analysing and understanding the fragmentation pattern of the mass spectrum of methoxymethane, characteristic pattern of peaks in the mass spectrum of methoxymethane, relative abundance of mass ion peaks in the mass spectrum of methoxymethane, revising the mass spectrum of methoxymethane, revision of mass spectroscopy of methoxymethane, most abundant ions in the mass spectrum of methoxymethane, how to construct the mass spectrum diagram for abundance of fragmentation ions in the mass spectrum of methoxymethane, how to analyse the mass spectrum of methoxymethane, how to describe explain the formation of fragmented ions in the mass spectra of methoxymethane equations for explaining the formation of the positive ions in the fragmentation of the ionised molecule of methoxymethane recognising the base ion peak of methoxymethane interpreting interpretation the mass spectrum of methoxymethane dimethyl ether Links associated with methoxymethane
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