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Advanced Level Organic Chemistry: Reaction mechanisms: acid/acyl chloride with ammonia/amines
10.7 Reaction of acid/acyl chlorides with ammonia and amines Doc Brown's Chemistry Advanced Level Pre-University Chemistry Revision Study Notes for UK KS5 A/AS GCE IB advanced level organic chemistry students US K12 grade 11 grade 12 organic chemistry GCE A Level Revision Notes PART 10 Summary of organic reaction mechanisms - A mechanistic introduction to organic chemistry and explanations of different types of organic reactions email doc brown - comments - query? Index of organic chemistry technical terms and mechanism pages All my revision notes on the chemistry of carboxylic acids & derivatives All my advanced A level organic chemistry notes Index of GCSE level oil and basic organic chemistry notes 10.7 Reaction of acid/acyl chlorides with ammonia and amines
10.7.1 Introduction to their reactivity Only acid chloride reactions are considered at the moment and the high reactivity of acyl chlorides is towards nucleophilic attack is due to the highly polarised situation of the carbon–oxygen/chlorine bonds i.e.
10.7.4 Amide formation via acyl chloride by nucleophilic addition–elimination
mechanism 16 – nucleophilic addition–elimination reaction for an acyl chloride forming an amide from ammonia
keywords phrases: reaction conditions formula intermediates organic chemistry reaction mechanisms nucleophilic addition elimination R–COCl + 2NH3 ==> R–CONH2 + NH4+ + Cl– R–COCl + 2R'NH2 ==> R–CONHR' + RNH3+ + Cl– R–COCl + R'NH2 ==> R–CONHR' + HCl COMPLETE MECHANISM and Organic Synthesis INDEX (so far!)
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