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Part 8.
The chemistry of Organic Nitrogen Compounds
Doc
Brown's Chemistry Advanced Level Pre-University Chemistry Revision Study
Notes for UK KS5 A/AS GCE IB advanced A level organic chemistry students US
K12 grade 11 grade 12 organic chemistry of organonitrogen compounds
INDEX of Organic Nitrogen Compound Notes
When I finally reached
organo-nitrogen compounds I'd already written much of the
chemistry of them in other sections.
SO, here I've linked to previous notes on other parts of my website, BUT added
extra notes where appropriate.
8.1
Molecular structure and nomenclature of
nitrogen containing organic
compounds
(Also includes an introduction as to how
to write and display organic-nitrogen formulae including isomers)
8.2
The
structure, classification and physical properties of aliphatic amines
8.3
Methods of synthesising amines (aliphatic and aromatic),
includes reactions of amines with halogenoalkanes
8.4
Acid-base chemistry of aliphatic amines, their comparative strength as bases
and reactions with acids
8.5
The
chemistry of amides e.g. formation from reacting acid chlorides and acid anhydrides
with amines,
polyamides - e.g. Nylon formation, structure, properties and uses
8.6
The
complexing reaction of primary aliphatic amines with d-block metal ions
(transition metal complexes)
8.7
Amine
bases and the hydrogen bonding in DNA and RNA
8.8
LINKS to all my
advanced level notes on amino acids, peptides, polypeptides and types
of proteins
8.9
Occurrence of organo-nitrogen
compounds in nature and pharmaceutical products
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AND other
IMPORTANT pages involving organonitrogen compounds
Section 6.11
Amides
- molecular structure, preparations and reactions, uses, brief mention of
polyamides
Section 6.12
The chemistry of nitriles - molecular
structure, preparations and reactions
Section 6.13
Amino acids - molecular
structure, preparation and reactions - two functional groups
Section 6.14
More on the uses of carboxylic acids
and derivatives and occurrence in
nature Section 7.10
The
chemistry of aromatic amines including preparation of phenylamine,
acylation, electrophilic substitution and azo dyes
and
Amino
acids as a case study of R/S isomerism
also
infrared, mass, 1H NMR
and 13C NMR spectra of specific organo-nitrogen compounds
Nitrogen
compounds covered in My Organic Chemistry Part 8:
Aliphatic and aromatic Primary amines .. Secondary amines .. Tertiary
Amines .. Quaternary ammonium salts ..
Amino acids and zwitterions ..
Primary acid amides .. Secondary acid amides .. Tertiary acid amides ...
Polyamides (Nylons and Kevlars) .. Diazonium salts and azo dyes ..
Nitro-aromatics .. Nitriles ...
Amino acids, peptides, polypeptides, proteins,
hydrogen bonds between bases in the structure of DNA and RNA
(mpt. = melting point; bpt. = boiling point; dec. = decomposes
on heating;
sub. = sublimes on heating)
The following notes have
basic reaction conditions, reagents and general equations as well as
notes on the mechanisms indicated and were written before
the above notes on the chemistry of organic nitrogen compounds.
Nucleophilic
substitution by cyanide ion to give a nitrile
[SN1 or SN2]
Nucleophilic
substitution by ammonia/primary amine to give primary/secondary
amines etc.
[SN1 or SN2]
Nucleophilic addition of
hydrogen cyanide to form a hydroxy-nitrile
Amide formation from reaction
of acid chlorides with ammonia
or primary amines
Nitration of arenes to give
nitro-aromatics like nitrobenzene
All Advanced A Level Organic
Chemistry Notes
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*
THE SPECTRA OF ORGANIC
COMPOUNDS * |
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Infrared spectra of organonitrogen compounds
The infrared NMR spectrum of
methylamine
infrared spectra of isomers of molecular formula
C2H7N
The infrared
spectrum of ethylamine
The infrared spectrum of
dimethylamine
infrared spectra of isomers
of molecular formula C3H9N
The infrared spectrum of
propylamine (propan-1-amine, 1-aminopropane)
The infrared spectra of
propan-2-amine (2-aminopropane, 2-propylamine, isopropylamine)
The infrared spectra
of N-methylethylamine (N-methylethanamine, ethylmethylamine)
The infrared spectra of
N,N-dimethylmethanamine (N.N-dimethylmethylamine, trimethylamine)
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Mass spectra of
organonitrogen compounds
The mass spectrum of methylamine
mass spectra of
isomers of molecular formula
C2H7N
The mass
spectrum of ethylamine
The mass
spectrum of dimethylamine
mass spectra of
isomers of molecular formula
C3H9N
The mass spectrum of propylamine
(propan-1-amine, 1-aminopropane)
The mass
spectra of propan-2-amine (2-aminopropane,
2-propylamine, isopropylamine)
The mass
spectra of N-methylethylamine (N-methylethanamine,
ethylmethylamine)
The mass
spectra of N,N-dimethylmethanamine
(N.N-dimethylmethylamine, trimethylamine)
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H-1 NMR spectra of
organonitrogen compounds
The H-1 NMR spectrum of
methylamine
H-1 NMR spectra isomers molecular formula C2H7N
The H-1 NMR spectrum of
ethylamine
The H-1 NMR spectrum
of dimethylamine
H-1 NMR spectra isomers
molecular formula C3H9N
The H-1 NMR
spectrum of propylamine (propan-1-amine, 1-aminopropane)
The H-1 NMR
spectra of propan-2-amine (2-aminopropane, 2-propylamine,
isopropylamine)
The H-1 NMR spectra
of N-methylethylamine (N-methylethanamine, ethylmethylamine)
The H-1 NMR spectra
of N,N-dimethylmethanamine (N.N-dimethylmethylamine,
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C-13 NMR
spectra of
organonitrogen compounds
The C-13 NMR spectrum of
methylamine
C-13 NMR spectra isomers
molecular formula C2H7N
The C-13 NMR spectrum of
ethylamine
The C-13 NMR spectrum
of dimethylamine
C-13 NMR spectra isomers
molecular formula C3H9N
The C-13 NMR spectrum
of propylamine (propan-1amine, 1-aminopropane)
The C-13 NMR
spectra of propan-2-amine (2-aminopropane, 2-propylamine,
isopropylamine)
The C-13 NMR
spectra of N-methylethylamine (N-methylethanamine,
ethylmethylamine)
The C-13 NMR spectra
of N,N-dimethylmethanamine (N.N-dimethylmethylamine,
trimethylamine)
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All Advanced A Level Organic
Chemistry Notes
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