A level inorganic chemistry: 3d block-transition metal complex ions & hydroxide precipitates
Appendix 12 Complex and hydroxide precipitate 'pictures' Some 'test tube' pictures of a variety of soluble transition metal complex ions and precipitates of insoluble complexes.
Doc Brown's Chemistry Advanced Level Pre-University Chemistry Revision Study Notes for UK IB KS5 A/AS GCE advanced level inorganic chemistry students US K12 grade 11 grade 12 inorganic chemistry - 3d block transition metal chemistry Sc Ti V Cr Mn Fe Co Ni Cu Zn |
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INORGANIC Part 10 3d block TRANSITION METALS sub–index: 10.1–10.2 Introduction 3d–block Transition Metals * 10.3 Scandium * 10.4 Titanium * 10.5 Vanadium * 10.6 Chromium * 10.7 Manganese * 10.8 Iron * 10.9 Cobalt * 10.10 Nickel * 10.11 Copper * 10.12 Zinc * 10.13 Other Transition Metals e.g. Ag and Pt * Appendix 1. Hydrated salts, acidity of hexa–aqua ions * Appendix 2. Complexes & ligands * Appendix 3. Complexes and isomerism * Appendix 4. Electron configuration & colour theory * Appendix 5. Redox equations, feasibility, Eø * Appendix 6. Catalysis * Appendix 7. Redox equations * Appendix 8. Stability Constants and entropy changes * Appendix 9. Colorimetric analysis and complex ion formula * Appendix 10 3d block – extended data * Appendix 11 Some 3d–block compounds, complexes, oxidation states & electrode potentials * Appendix 12 Hydroxide complex precipitate 'pictures', formulae and equations Advanced Level Inorganic Chemistry Periodic Table Index * Part 1 Periodic Table history * Part 2 Electron configurations, spectroscopy, hydrogen spectrum, ionisation energies * Part 3 Period 1 survey H to He * Part 4 Period 2 survey Li to Ne * Part 5 Period 3 survey Na to Ar * Part 6 Period 4 survey K to Kr and important trends down a group * Part 7 s–block Groups 1/2 Alkali Metals/Alkaline Earth Metals * Part 8 p–block Groups 3/13 to 0/18 * Part 9 Group 7/17 The Halogens * Part 10 3d block elements & Transition Metal Series * Part 11 Group & Series data & periodicity plots * All 11 Parts have their own sub–indexes near the top of the pages Appendix 12 PICTURES of PRECIPITATES and COMPLEX FORMATION Prior to, and with, excess reagent for selected 3d block aqueous ions. They can be used as simple tests for identifying transition metal ions.
Text and formula summary of these reactions of 3d block ions is given below but there are more details in most cases in the notes for each metal for ... [M(H2O)6]n+ where M = metal, n = 2 or 3 and Al3+ for comparison (See Chemical Tests for more precipitates) ... and many are useful simple tests to identify metal ions (ppt. = precipitate, gel. = gelatinous)
For detailed equations of these reactions go to the specific chemistry sections for that metal via the index below Scandium * Titanium * Vanadium * Chromium * Manganese * Iron * Cobalt * Nickel * Copper * Zinc * Silver & Platinum
The comparison equations for the aluminium ion (NOT a 3d block metal)
Scandium * Titanium * Vanadium * Chromium * Manganese * Iron * Cobalt * Nickel * Copper * Zinc * Silver & Platinum Introduction 3d–block Transition Metals * Appendix 1. Hydrated salts, acidity of hexa–aqua ions * Appendix 2. Complexes & ligands * Appendix 3. Complexes and isomerism * Appendix 4. Electron configuration & colour theory * Appendix 5. Redox equations, feasibility, Eø * Appendix 6. Catalysis * Appendix 7. Redox equations * Appendix 8. Stability Constants and entropy changes * Appendix 9. Colorimetric analysis and complex ion formula * Appendix 10 3d block – extended data * Appendix 11 Some 3d–block compounds, complexes, oxidation states & electrode potentials * Appendix 12 Hydroxide complex precipitate 'pictures', formulae and equations |
Doc Brown's Chemistry |
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