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Problem solving revision questions on redox volumetric titration calculations for Advanced Inorganic Chemistry
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Doc Brown's Advanced Level Quantitative Chemistry Quantitative redox reaction analysis GCE Advanced A Level REDOX Volumetric Analysis Titration Revision QUESTIONS email doc brown - comments - query? All my advanced A level inorganic chemistry revision notes Use your mobile phone or ipad etc. in 'landscape' style This is a BIG website, you need to take time to explore it [SEARCH BOX] Equations needed * FULL ANSWERS and WORKING * REDOX REACTION THEORY * Qualitative Analysis and also acid–base and other non–redox titrations Questions * EMAIL query?comment?error Quantitative volumetric analysis – exam practice redox titration questions based potassium manganate(VII)–iron(II)/ethanedioate–ethanedioic acid (oxalate, oxalic acid)/hydrogen peroxide/sodium nitrite titrations, sodium thiosulfate/thiosulfate–iodine titrations and potassium dichromate(VI)–iron(II) titration. Any suggestions for additional types of A level redox titration questions?
Volumetric analysis worksheet of structured questions of REDOX VOLUMETRIC TITRATION CALCULATIONS Titrations and calculations based on oxidation–reduction techniques–reactions – solved problems Relative atomic masses that may be needed, in alphabetical order of symbol ... C=12.0, Cr = 52.0, Fe=55.9, H=1.0, I=126.9, K=39.1, Mn=54.9, N=14.0, Na=23.0, O=16.0, S=32.1, NOTE: Half reactions are usually quoted as the half–cell reduction equation. Reuse half–cell or full equations in later questions from earlier questions. It is assumed you will work through them in numerical question order. If you cannot work out the redox equations, you can just download the equations so that you can at least practice the 'pure' volumetric calculation aspects of the questions. Questions 1/4/6/7/8/9/10/11/12/13/15/16 based potassium manganate(VII)–iron(II)/ethanedioate–ethanedioic acid (oxalate, oxalic acid)/hydrogen peroxide/sodium nitrite titrations, Q2/14/17 on sodium thiosulfate–iodine titration, Q3/5 on potassium dichromate(VI)–iron(II) titration, further Q's will be added – suggestions? REDOX–ionic EQUATION CHECKS
I've tried to quote the data to the appropriate significant figures and associated 'trailing zeros'. Note that it is standard convention to show half-cell reactions as reductions, i.e. atom/ion/molecule + electrons to give the reduction product. This means you have to judge whether the half-reaction needs to be reversed to derive the full ionic redox equation, and any multiples of it are needed, - so take care, and don't get confused by conventions! they are there help! I DO MY BEST TO CHECK MY CALCULATIONS, as you yourself should do, BUT I AM HUMAN! AND IF YOU THINK THERE IS A 'TYPO' or CALCULATION ERROR PLEASE EMAIL ME ASAP TO SORT IT OUT! Question 1: Given the following two half–reactions: (Q1 can be done as an experimental 'word–fill' version) Question 1 has many parts covering the titration of iron(II) ions with a standard solution of potassium manganate(VII) and the problems are solved.
(i) MnO4–(aq) + 8H+(aq) + 5e– ==> Mn2+(aq) + 4H2O(l) and (ii) Fe3+(aq) + e– ==> Fe2+(aq) (a) Construct the fully balanced redox ionic equation for the manganate(VII) ion oxidising the iron(II) ion (b) 24.3 cm3 of 0.0200 mol dm–3 KMnO4 reacted with 20.0 cm3 of an iron(II) solution acidified with dilute sulfuric acid.
(c) Calculate the percentage of iron in a sample of steel wire if 1.51 g of the wire was dissolved in excess of dilute sulfuric acid and the solution made up to 250 cm3 in a standard graduated flask.
(d) Suggest reasons why the presence of dil. sulfuric acid is essential for an accurate titration and why dil. hydrochloric and nitric acids are unsuitable to be used in this context. (e) The analysis of a soluble iron(II) salt to obtain the percentage of iron in it.
Question 2: Given the following two half–reactions (a) Given (i) S4O62–(aq) + 2e– ==> 2S2O32–(aq) and (ii) I2(aq) + 2e– ==> 2I–(aq) construct the full ionic redox equation for the reaction of the thiosulfate ion S2O32– and iodine I2. (b) what mass of iodine reacts with 23.5 cm3 of 0.0120 mol dm–3 sodium thiosulfate solution.
(c) 25.0 cm3 of a solution of iodine in potassium iodide solution required 26.5 cm3 of 0.0950 mol dm–3 sodium thiosulfate solution to titrate the iodine. What is the molarity of the iodine solution and the mass of iodine per dm3?
Question 3: 2.83 g of a sample of haematite iron ore [iron (III) oxide, Fe2O3] were dissolved in concentrated hydrochloric acid and the solution diluted to 250 cm3. 25.0 cm3 of this solution was reduced with tin(II) chloride (which is oxidised to Sn4+ in the process) to form a solution of iron(II) ions. This solution of iron(II) ions required 26.4 cm3 of a 0.0200 mol dm–3 potassium dichromate(VI) solution for complete oxidation back to iron(III) ions. (a) given the half–cell reactions (i) Sn4+(aq) + 2e– ==> Sn2+(aq) and (ii) Cr2O72–(aq) + 14H+(aq) + 6e– ==> 2Cr3+(aq) + 7H2O(l) deduce the fully balanced redox equations for the reactions
(b) Calculate the percentage of iron(III) oxide in the ore.
(c) Suggest why potassium manganate(VII) isn't used for this titration? (though it was ok in Q1)
Question 4: An approximately 0.02 mol dm–3 potassium manganate(VII) solution was standardized against precisely 0.100 mol dm–3 iron(II) ammonium sulfate solution. 25.0 cm3 of the solution of the iron(II) salt were oxidized by 24.15 cm3 of the manganate(VII) solution.
Question 5: 10.0 g of iron(II) ammonium sulfate crystals were made up to 250 cm3 of acidified aqueous solution. 25.0 cm3 of this solution required 21.25 cm3 of 0.0200 mol dm–3 potassium dichromate(VI) for oxidation.
Question 6: Given the half–reaction C2O42–(aq) – 2e– ==> 2CO2(g)
(a) write out the balanced redox equation for manganate(VII) ions oxidising the ethanedioate ion (or ethanedioic acid). (b) 1.520 g of hydrated ethanedioic acid crystals, H2C2O4.2H2O, was made up to 250.0 cm3 of aqueous solution and 25.00 cm3 of this solution needed 24.55 cm3 of a potassium manganate(VII) solution for oxidation.
Question 7: A standardization of potassium manganate(VII) solution yielded the following data: 0.150 g of the salt potassium tetraoxalate dihydrate, KHC2O4.H2C2O4.2H2O needed 23.20 cm3 of the manganate(VII) solution.
Question 8: Given the half–cell equations: (i) O2(g) +2H+(aq) + 2e– ==> H2O2(aq)
(a) construct the fully balanced redox ionic equation for the oxidation of hydrogen peroxide by potassium manganate(VII) (b) 50.0 cm3 of solution of hydrogen peroxide were diluted to 1.00 dm3 with water.
Question 9: 13.2 g of iron(III) alum were dissolved in water and reduced to an iron(II) ion solution by zinc and dilute sulfuric acid. The mixture was filtered and the filtrate and washings made up to 500 cm3 in a standard volumetric flask.
Question 10: Calculate the concentration in mol dm–3 and g dm–3, the salt sodium ethanedioate (Na2C2O4) solution, 5.00 cm3 of which were oxidized in acid solution by 24.50 cm3 of a potassium manganate(VII) solution containing 0.05 mol dm–3.
Question 11: Calculate x in the formula FeSO4.xH2O from the following data:
Question 12: Given the half–reaction equation:
Question 13: 2.68 g of the salt iron(II) ethanedioate, FeC2O4, were made up to 500 cm3 of acidified aqueous solution. 25.0 cm3 of this solution reacted completely with 28.0 cm3 of 0.0200 mol dm–3 potassium manganate(VII) solution.
Question 14: Given the half–cell reactions:
Question 15: Calculate the molarities of iron(II) and iron(III) ions in a mixed solution from the following data.
(i) 25.0 cm3 of the original mixture was acidified with dilute sulfuric acid and required 22.5 cm3 of 0.0200 mol dm–3 KMnO4 for complete oxidation.
(ii) a further 25.0 cm3 of the original iron(II)/iron(III) mixture was reduced with zinc and acid and it then required 37.6 cm3 of the KMnO4 for complete oxidation.
Question 16: A piece of rusted iron was analysed to find out how much of the iron had been oxidised to rust [hydrated iron(III) oxide].
Question 17: 25.0 cm3 of an iodine solution was titrated with 0.100 mol dm–3 sodium thiosulfate solution and the iodine reacted with 17.6 cm3 of the thiosulfate solution.
Question 18: 1.01g of an impure sample of potassium dichromate(VI), K2Cr2O7, was dissolved in dil. sulfuric acid and made up to 250 cm3 in a calibrated volumetric flask.
Question 19: This question involves titrating ethanedioic acid (oxalic acid), H2C2O4 or (COOH)2 (i) with standard sodium hydroxide solution and then with potassium manganate(VII) solution (potassium permanganate, KMnO4). The titration data is as follows:
Question 20 Lawn sand containing the salt iron(II) sulfate is used to treat moss.
Question 21 Analysing a medicinal iron tablet containing an iron(II) salt.
Question 22 ?
I DO MY BEST TO CHECK MY CALCULATIONS, as you yourself should do, BUT I AM HUMAN! AND IF YOU THINK THERE IS A 'TYPO' or CALCULATION ERROR PLEASE EMAIL ME ASAP TO SORT IT OUT! practice redox titration questions, how do you do redox titrations? how do you do redox titration calculations? what apparatus do you need to do redox titrations? describe redox titration methods and procedures, what is the definition of a redox titration? how to do redox titration experiments, describe examples of redox titrations, (potassium permanganate) potassium manganate(VII) - iron iron(II) sulfate titration calculation method, sodium thiosulfate Na2S2O3 - I2 iodine titration calculation method, potassium manganate(VII) - iron(II) ammonium sulfate (ferrous ammonium sulfate) standardising titration calculation method, potassium manganate(VII) - ethanedioic acid (oxalic acid) titration calculation method, KMnO4 - potassium tetraoxalate dihydrate titration calculation method, hydrogen peroxide H2O2 KMnO4 potassium manganate (VII) titration calculation method, potassium manganate(VII) KMnO4 - sodium ethanedioate Na2C2O4 titration calculation method, determining water of crystallisation in FeSO4 hydrated iron(II) sulfate, KMnO4 potassium manganate(VII) - nitrite nitrate(III) potassium nitrite titration calculation method, potassium manganate (VII) - iron(II) ethanedioate FeC2O4 titration calculation method, KIO3 potassium iodate iodate(V) - iodine - sodium thiosulfate titration calculation method, analysing iron content of rust or iron ore iron(III) oxide Fe2O3 with potassium manganate(VII) titration calculation method, analysing potassium dichromate dichromate(VI) by oxidising iodide to iodine and titrating iodine with Na2S2O3 sodium thiosulfate keywords–phrases etc.: MnO4–(aq) + 8H+(aq) + 5Fe2+(aq) ==> Mn2+(aq) + 5Fe3+(aq) + 4H2O(l) * 2S2O32–(aq) + I2(aq) ==> S4O62–(aq) + 2I–(aq) * Cr2O72–(aq) + 14H+(aq) + 6Fe2+(aq) ==> 2Cr3+(aq) + 6Fe3+(aq) + 7H2O(l) * 2MnO4–(aq) + 16H+(aq) + 5C2O42–(aq) ==> 2Mn2+(aq) + 8H2O(l) + 10CO2(g) or 2MnO4–(aq) + 6H+(aq) + 5H2C2O4(aq) ==> 2Mn2+(aq) + 8H2O(l) + 10CO2(g) * 2MnO4–(aq) + 6H+(aq) + 5H2O2(aq) ==> 2Mn2+(aq) + 8H2O(l) + 5O2(g) * 2MnO4–(aq) + 6H+(aq) + 5NO2–(aq) ==> Mn2+(aq) + 5NO3–(aq) + 3H2O(l) * IO3–(aq) + 5I–(aq) + 6H+(aq) ==> 3I2(aq) + 3H2O(l) * Cr2O72–(aq) + 14H+(aq) + 6I–(aq) ==> 2Cr3+(aq) + 3I2(aq) + 7H2O(l) * MnO4– + 8H+ + 5Fe2+ ==> Mn2+ + 5Fe3+ + 4H2O * 2S2O32– + I2 ==> S4O62– + 2I– * Cr2O72– + 14H+ + 6Fe2+ ==> 2Cr3+ + 6Fe3+ + 7H2O * 2MnO4– + 16H+ + 5C2O42– ==> 2Mn2+ + 8H2O + 10CO2 or 2MnO4– + 6H+ + 5H2C2O4 ==> 2Mn2+ + 8H2O + 10CO2 * 2MnO4– + 6H+ + 5H2O2 ==> 2Mn2+ + 8H2O + 5O2 * 2MnO4– + 6H+ + 5NO2– ==> Mn2+ + 5NO3– + 3H2O * IO3– + 5I– + 6H+ ==> 3I2 + 3H2O * Cr2O72– + 14H+ + 6I– ==> 2Cr3+ + 3I2 + 7H2O advanced level chemistry redox titration questions for AQA AS chemistry, redox titration questions for Edexcel A level AS chemistry, redox titration questions for A level OCR AS chemistry A, redox titration questions for OCR Salters AS chemistry B, redox titration questions for AQA A level chemistry, redox titration questions for A level Edexcel A level chemistry, redox titration questions for OCR A level chemistry A, redox titration questions for A level OCR Salters A level chemistry B redox titration questions for US Honours grade 11 grade 12 redox titration questions for pre-university chemistry courses pre-university A level revision notes for redox titration questions A level guide notes on redox titration questions for schools colleges academies science course tutors images pictures diagrams for redox titration questions A level chemistry revision notes on redox titration questions for revising module topics notes to help on understanding of redox titration questions university courses in science careers in science jobs in the industry laboratory assistant apprenticeships technical internships USA US grade 11 grade 11 AQA A level chemistry notes on redox titration questions Edexcel A level chemistry notes on redox titration questions for OCR A level chemistry notes WJEC A level chemistry notes on redox titration questions CCEA/CEA A level chemistry notes on redox titration questions for university entrance examinations with advanced level chemistry [SEARCH BOX] |
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