Advanced Organic Chemistry: Mass spectrum of propylamine
The mass spectrum of propylamine (1-aminopropane)
Doc Brown's Chemistry Advanced Level Pre-University Chemistry Revision Study Notes for UK IB KS5 A/AS GCE advanced A level organic chemistry students US K12 grade 11 grade 12 organic chemistry courses involving molecular spectroscopy analysing mass spectra of propylamine
propylamine, (1-aminopropane), C3H9N, , ,
Interpreting the fragmentation pattern of the mass spectrum of propylamine
[M]+ is the molecular ion peak (M) with an m/z of 59 corresponding to [C3H9N]+, the original propylamine molecule minus an electron, [CH3CH2CH2NH2]+.
The tiny M+1 peak at m/z 60, corresponds to an ionised propylamine molecule with one 13C atom in it i.e. an ionised propylamine molecule of formula 13C12C2H9N
Identifying the species giving the most prominent peaks (apart from M) in the fragmentation pattern of propylamine.
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