
WHY ARE THERE SO MANY SERIES of ORGANIC
COMPOUNDS?
8. Introduction to General Organic Chemistry - Why is there such a variety of
organic compounds?
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8.
Why are there many families of
organic compounds?
- variety !
(gcse revision notes on homologous
series and functional groups for GCSE 9-1 chemistry exams)
Homologous Series and Functional Groups
(gcse revision notes on homologous
series and functional groups for GCSE 9-1 chemistry exams)
You need to be able to explain that the vast array of natural and synthetic
organic compounds occur due
to the ability of carbon to form families of similar compounds, 'linear'
straight chains, branched chains and rings of carbon atom all strongly bond in a
variety ways with other carbon atoms and (usually) non-metallic elements
including hydrogen, oxygen and nitrogen in particular e.g.
a
linear chain alkane hydrocarbon, just carbon and hydrogen atoms in this organic
molecule
a branched chain hydrocarbon, just
carbon and hydrogen atoms (also an alkane, methylpropane)
a
hydrocarbon ring compound of carbon and hydrogen atoms (its called cyclohexane,
a cyclic alkane)
an
organic compound of carbon, hydrogen and oxygen atoms (ethanoic acid, a
carboxylic acid)
an
organic compound of carbon, hydrogen, nitrogen and oxygen atoms (an amino acid,
aminoethanoic acid)
Most food is chemically
organic in nature, apart from some minerals, and many drugs and plastic
materials are composed of organic molecules, consequently, organic compounds
and organic chemistry is rather important to us!
The term
organic compound comes from the fact that most of the original organic compounds studied
by scientists-chemists came from plants or animals, i.e. of natural origin.
These days most organic compounds are synthesised from raw materials, in
particular the physical separation and chemical manipulation of the products
of crude petroleum oil.
The vast array of organic compounds, both natural and
synthetic carbon compounds, occur due to the ability of carbon atoms to form
families of similar compounds.
The compounds in each family have a similar chemical structure and a similar chemical
formula. Each family of organic compounds forms what is called a homologous
series. and all the members behave in the same chemical way i.e. they
have a common set of reactions.
Different families arise because carbon atoms readily join together in
chains (catenation) and strongly bond with other atoms such as hydrogen,
oxygen and nitrogen.
The result is a huge variety of 'organic compounds'
which can be classified into groups of similar compounds i.e. different
homologous series with particular similarities (more on this below).
(gcse revision notes on
homologous series and functional groups for GCSE 9-1 chemistry exams)
'Probably' before reading this page, you should have already been introduced to
at least two series of
organic molecules, such as the hydrocarbons called alkanes and alkenes, which illustrate the fact that organic chemistry is
the chemistry of carbon based compounds, but first we need to explain what
we mean by the terms homologous series and functional group.
- A homologous series is a family of
compounds which have the same general formula (*) and have
a similar molecular structure and similar chemical
properties because they have the same functional group of atoms (e.g.
C=C alkene, C-OH alcohol or -COOH carboxylic acid).
- (*) Some
examples of general formula and the functional group for four
homologous series of organic molecules
- These examples are based on a chain of just two
carbons atoms, but the amply illustrate the four homologous series
described.
-
Homologous series of alkanes CnH2n+2,
where n = 1, 2, 3 etc. number of carbon atoms in the molecule
- The diagram shows ethane, the 2nd in the
series
- Alkanes don't really have a functional group
like most other homologous series.
-
Homologous series of alkenes CnH2n,
where n = 2, 3, 4 etc. number of carbon atoms in the molecule
- Here the functional group is the carbon -
carbon double bond, >C=C<
- The diagram shows ethene, the 1st in the
series
-
Homologous series of
alcohols CnH2n+1OH,
where n = 1, 2, 3 etc. number of carbon atoms in the molecule
- Here the functional group is the hydroxy
group attached to a carbon atom, C-O-H
- The diagram shows ethanol, the 2nd in the
series
-
Homologous series of carboxylic acids CnH2n+1COOH,
where n = 0, 1, 2 etc. number of carbon atoms in the molecule minus 1
- Here the functional group is, COOH, a
combination of one carbon, two oxygen and one hydrogen atom.
- The diagram shows ethanoic acid, the 2nd in
the series
Some more examples of the molecular
structure of some homologous series you will come across ...
(e.g. in your GCSE/IGCSE chemistry science
courses).
Hydrocarbons like
alkanes
like
butane, 4th in the alkane homologous series,
and
alkenes like
propene, the 2nd in the alkene
homologous series
which form two so called 'homologous
series' or organic chemical compounds.
Advanced A Level revision notes on the
structure & naming of ALKANES
Advanced A Level revision notes on the structure
and naming of ALKENES
but there are many more series of organic
molecules, so why such variety of organic molecules?
(gcse revision notes on
homologous series and functional groups for GCSE 9-1 chemistry exams)
Organic compounds belong to different
families called homologous series, though all organic compounds are based on
carbon C,
and usually hydrogen H, the carbon atoms do combine with other
elements e.g.
oxygen O e.g.
alcohols
like methanol
, the 1st in the alcohol homologous series,
hydroxy functional group -OH
Advanced A Level revision notes on the structure and naming of ALCOHOLS
carboxylic acids like
propanoic
acid, 3rd in the carboxylic acid homologous series, functional group is
-COOH
Advanced Level
revision notes on the
structure and naming of CARBOXYLIC ACIDS & ESTERS
and esters
like
ethyl ethanoate, in the ester homologous series
nitrogen N e.g. in H2NCH2COOH the simplest
of the
amino acids
halogens like fluorine, chlorine, bromine
and iodine can combine with carbon e.g.
chloromethane,
no
hydrogen!,
bromoethane,
producing lots of homologous series like chloro-alkanes etc.
Advanced Level revision notes
on the structure and naming of HALOGENOALKANES
Simplified displayed formula for the first four or five members of the four
homologous series of
organic compounds you are likely to come across (UK GCSE level
chemistry students)
alkanes have no functional group, alkenes
have the >C=C< double bond functional group,
alcohols have the C-OH functional group and
carboxylic acids have the -COOH functional group
Notice as you move from one
member of a homologous series to the next, you add on an extra -CH2-
unit
Carboxylic acids
The two series of
displayed formulae
for alkenes and carboxylic acids
are a more accurate representation of the structure of the carboxylic acid
molecules
Some
notes on molecular formula and molecular structure
(gcse revision notes on
homologous series and functional groups for GCSE 9-1 chemistry exams)
- The molecular formula represents a summary
of all the atoms in the molecule e.g. butane is C4H10.
- The structural formula or displayed formula shows
the full structure of the molecule with all the individual bonds and atoms
shown (though there are different 'sub-styles' of varying detail)
- e.g.
all represent ethane
- The full displayed formula must show all the
bonds in the molecule so that connection between every atom can be clearly
seen, as in the 3rd and 4th diagrams above, and the other examples below.
- When a specific group of atoms in a
molecule give it a particular set of characteristic chemical reactions, that group of
atoms is called the functional group of the molecule. Examples of
functional groups include:
- the double carbon-carbon bond
>C=C< in
alkenes,
- eg
and
-
the oxygen-hydrogen atom group of
the C-OH structure in
alcohols,
- eg
and
- and
the group of four atoms
constituting the -COOH and -COOC- groups in
carboxylic acids and esters
respectively.
- eg carboxylic acid
and ester
- NOTE: Inorganic
compounds are all the other compounds not based on carbon, except for
carbon monoxide CO, carbon dioxide CO2 and carbonates, which are
also considered
to be inorganic.
- Examples of inorganic compounds: water
H2O,
ammonia NH3,
sodium chloride NaCl, calcium carbonate CaCO3
Multiple Choice Quizzes and Worksheets
KS4 Science GCSE/IGCSE m/c QUIZ on Oil Products
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KS4 Science GCSE/IGCSE m/c QUIZ on other aspects of Organic Chemistry
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14-16
gcse chemistry why lots of different organic molecules?
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