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2d. Describing and explaining the ionic bonding of the compounds magnesium chloride MgCl2 and calcium chloride CaCl2 e.g. ionic compounds formed by combining a group 2 alkaline earth metal with a group 7 halogen element [Author © Dr Phil Brown GRIC, PhD: Doc Brown's chemistry exam revision notes on the ionic bonds of magnesium chloride & calcium chloride, suitable for students of UK GCSE Science level AQA, Edexcel, OCR, WJEC Eduqas and CCEA GCSE chemistry courses, ~US grades 9-10 chemistry, also useful for more advanced pre-university A level chemistry courses [ionic bonding page RE-EDIT] GCSE Foundation tier (easier) m/c QUIZ on structure, properties & chemical bonding of materials GCSE Higher tier (harder) m/c QUIZ on structure, properties and chemical bonding of materials Index for ALL chemical bonding and structure notes Part 2 ionic index Ionic Bonding: compounds and properties All my GCSE level chemistry revision notes All my advanced level chemistry revision notes All my structure and bonding notes email doc brown * [privacy, cookies and disclaimer] Example 2d. A Group 2 Alkaline Earth Metal combining with a Group 7 Halogen non–metal
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e.g. magnesium + chlorine ==> magnesium chloride MgCl2 or ionic formula Mg2+(Cl–)2 In terms of electron arrangement in the formation of the ionic compound magnesium chloride, the magnesium donates its two outer electrons to two chlorine atoms forming a double positive magnesium ion and two single negative chloride ions via electron transfer.
Mg (2.8.2) + 2Cl (2.8.7) ==> Mg2+ (2.8) 2Cl– (2.8.8) can be summarised electronically as [2,8,2] + 2[2,8,7] ==> [2,8]2+ [2,8,8]–2 via electron transfer so both the magnesium and chloride ions have a full outer shell of electrons like a noble gas ONE to form Note in this electron diagram, only the original outer electrons are shown above. The outer electrons of the magnesium atoms (2.8.2) are transferred to the outer shell of the chlorine atom (2.8.7) giving it a complete octet shell of outer electrons, just like a noble gas (2.8.8). At the same time, the magnesium ion also attains a stable noble gas electron structure (2.8). NOTE
Note that the 'blob' and 'x' electrons are identical, but their use is just a useful visual device to show how the ion is formed. The blue circle represents the nucleus. The electronic dot & cross for the ionic bonding in the ionic compound magnesium chloride
is the simplified Lewis dot and cross diagram for the formation of magnesium chloride Melting point of magnesium chloride is 714oC (see extra comments after calcium chloride diagrams)
Ca is 2.8.8.2, Cl is 2.8.7, F is 2.7 rest of dot and cross diagrams are up to you, but calcium chloride is shown below. The calcium atoms transfer their two outer electrons to the outer shell of two chlorine atoms
The two outer electrons of the calcium atoms (2.8.8.2) are transferred to the outer shell of two chlorine atoms (2.8.7) until it has a complete octet shell of outer electrons, just like a noble gas (2.8.8). At the same time, the calcium ion also attains a stable noble gas electron structure (2.8.8). The blue circle represents the nucleus.
is the Lewis diagram for the formation of calcium chloride
Extra comments on magnesium chloride and calcium chloride Melting point of calcium chloride is 772oC and magnesium chloride is 714oC - very high and expected for a giant ionic lattice of a typical ionic compound with a strongly bonded 3D crystal lattice of alternating positive (calcium/magnesium) and negative ions (chloride) that strongly attract each other. This means the solid magnesium/calcium chloride particles need much higher kinetic energies of vibration to break apart from the giant ionic lattice to form a liquid. This means the solid magnesium/calcium chloride particles need much higher kinetic energies of vibration to break apart from the giant ionic lattice to form a liquid. Molten magnesium/calcium chloride will conduct electricity because the ions are free to move to carry the current and will undergo electrolysis to extract magnesium/calcium (or any group 2 metal and release chlorine (or any free Group 7 halogen element) from a similar salt. See also Using the ionic bonding model to describe and explain the properties of ionic compounds and for Advanced A-level students ONLY see thermodynamics sections Note group 7 = group 17 at advanced A-level theoretical-inorganic chemistry
Predicting formulae and names for combing a group 2 metal with a group 7 non-metal halogen
Learning objectives for the ionic compound formed by combining a group 2 alkali earth metal with a group 7 halogen non-metal element
What next? GCSE Foundation tier (easier) m/c QUIZ on structure, properties & chemical bonding of materials GCSE Higher tier (harder) m/c QUIZ on structure, properties and chemical bonding of materials Sub-index for: Part 2 Ionic Bonding: compounds and properties Index for ALL chemical bonding and structure notes |
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