Advanced Organic Chemistry: Infrared spectrum of ethyl methanoate (ethyl formate) HCOOCH2CH3

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Interpreting and explaining the infrared spectrum of ethyl methanoate (ethyl formate)

[Author © Dr Phil Brown PhD: Doc Brown's advanced level organic chemistry exam revision notes suitable for students of UK A level chemistry courses & US K12 grade 11, grade 12 and AP honors chemistry courses: Molecular spectroscopy - analysing the infrared spectra of ethyl methanoate [spectra page updated April 3rd 2026 *]

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Introductory note on the infrared spectrum of ethyl methanoate

Students and teachers please note my explanation of the infrared spectrum of ethyl methanoate is designed for advanced, but pre-university, chemistry courses.

Based in the infrared spectrum diagram for ethyl methanoate, only some of the most prominent peaks for particular bond vibrations are discussed, particularly if ethyl methanoate has a functional group with a particular characteristic wavenumber peak.

The infrared spectrum of ethyl methanoate is unique and the whole, or selected wavenumbers, can be used to fingerprint its identity, sometimes analysing a mixture containing ethyl methanoate or following its change of concentration in a reaction.

infrared spectrum of ethyl methanoate C3H6O2 HCOOCH2CH3 wavenumbers cm-1 functional group detection fingerprint pattern identification of ethyl methanoate doc brown's advanced organic chemistry revision notes 

Spectra obtained from a liquid film of ethyl methanoate. The right-hand part of the of the infrared spectrum of ethyl methanoate, wavenumbers ~1500 to 400 cm-1 is considered the fingerprint region for the identification of ethyl methanoate and most organic compounds. It is due to a unique set of complex overlapping vibrations of the atoms of the molecule of ethyl methanoate.

Ethyl methanoate (ethyl formate) C3H6O2  (c) doc b  (c) doc b  (c) doc b 

(c) doc b   The molecular structure and naming of carboxylic acids and derivatives

Interpretation of the infrared spectrum of ethyl methanoate

The most prominent infrared absorption lines of ethyl methanoate

C-H stretching vibration absorptions occur in the wavenumber region 2975 to 2860 cm-1.

Not very important, common to most organic molecules.

For saturated aliphatic esters, C=O stretching vibration absorptions occur in the wavenumber region 1750 to 1735 cm-1.

This is a very characteristic absorption for any molecule e.g. an ester, with a carbonyl group.

For methanoate esters, C-O stretching vibration absorptions occur in the wavenumber region 1200 to 1180 cm-1.

The absence of other specific functional group bands will show that a particular functional group is absent from the ethyl methanoate molecular structure e.g. no hydroxyl group vibration at ~3500 to 3200 cm-1., obviously not expected for an ester like methyl ethanoate, but expected for a carboxylic acid like the isomeric propanoic acid.


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Links associated with ethyl methanoate

The mass spectrum of ethyl methanoate (ethyl formate)

The H-1 NMR spectrum of ethyl methanoate (ethyl formate)

The C-13 NMR spectrum of ethyl methanoate (ethyl formate)

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