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Revision help links for IB Chemistry

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Doc Brown's Chemistry

International Baccalaureate Chemistry - Diploma Programme of IB Chemistry

My unofficial support for this IB chemistry syllabus-specification

email doc brown - comments - query?

ALL my advanced A level chemistry revision study notes

PAST PAPERS

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Links to revision note pages that may help with the core and option topics for Standard Level (SL) and Additional Higher Level (AHL), from which there are links to notes and quizzes etc. - Each topic or unit is linked to potentially useful sections on this site

READ CAREFULLY  PLEASE remember that despite the fact that my 'A level' chemistry notes are far from complete, and as yet, do not even cover all the basics, but I think there is enough to start an unofficial support page. By clicking on the text and [ORGANIC], [INORGANIC], [PHYSICAL-THEORETICAL] and [useful GCSE/IGCSE O level notes] icon links you should find things to help on a particular topic.  The notes-quizzes are not just for your particular syllabus, but are designed to cover, eventually, any Chemistry in UK based advanced level pre-university chemistry specification so you need to pick out the bits which are useful for your syllabus. [Each link opens up in a new window] [ALL LINKS SHOULD WORK IF THIS PAGE IS SAVED]


INDEX of syllabus-specification section links

Core Topics 1 to 12 for Standard Level and Additional Higher Level

Topic 1 Stoichiometric relationships - Quantitative Chemistry

Topic 2 Atomic structure

Topic 3 Periodicity

Topic 4 Chemical bonding and structure

Topic 5 Energetics - thermochemistry

Topic 6 Chemical Kinetics

Topic 7 Equilibrium

Topic 8 Acids and bases

Topic 9 Redox processes - oxidation and reduction

Topic 10 Organic Chemistry

Topic 11 Measurement and Data Processing

Additional Higher Level Topics 12 to 20

Topic 12 Atomic structure

Topic 13 The periodic table - transition metals

Topic 14 Chemical bonding and structure

Topic 15 Energetics - thermochemistry

Topic 16 Chemical kinetics

Topic 17 Equilibrium

Topic 18 Acids and Bases

Topic 19 Redox processes - oxidation and reduction

Topic 20 Organic Chemistry

Topic 21 Measurement and data processing

Options - just a selection

Option A: Materials

Option B: Biochemistry

Option C: Energy

Option D: Medicinal chemistry


Core Topics 1 to 11 for Standard Level and Additional Higher Level

(just some selected links that might be of use - but nothing like the same cover of the 20 topics above)


Topic 1 Stoichiometric relationships - Quantitative Chemistry  (Core IB Chemistry topic)

Chemical Calculations index - 1. to 16. sections of explanation-examples and quizzes built into the notes

section 7. introducing moles

(c) doc b section 8. Using moles to deduce empirical/molecular formula of a compound/molecule

How to understand and write chemical equations including ionic equations and work out molecular and ionic formulae from valencies or ion charges

section 9. moles and molar gas volume

section 6. on reacting mass and % & theoretical yield

section 14. % & theoretical yield, volumetric apparatus & dilution calculations

(c) doc b section 16. Gas calculations involving PVT relationship and PV = nRT

section 11. making up solutions, concentration & molarity

section 12. acid-alkali titration calculations - apparatus/analysis

States of Matter Part 1: gas-liquid-solid BASIC revision notes

States of Matter Part 2: More advanced topics on the Ideal Gas Laws, p-V-T calculations

States of Matter Part 3: PV=nRT calculations, kinetic particle model-theory and ideal and non-ideal real gas behaviour


Topic 2 Atomic structure (Core IB Chemistry topic)

GCSE Atomic Structure Notes including mass spectrometry of elements - the structure of atoms, isotopes, nuclear structure notation, 'simple' electronic structure and the Periodic Table

GCSE multiple choice quiz on  Atomic structure, isotopes & 'simple' electronic structure of atoms

Radioactivity and Nuclear Power - includes properties and uses of alpha, beta and gamma radiation, radioisotope dating, half-life etc.

Introduction to mass spectrometry

Emission and absorption spectroscopy

Periodic Table Advanced Inorganic Chemistry Notes Part 2 "Electronic Structure and Ionisation Energies" - includes section on hydrogen spectrum and emission spectroscopy

Electron configurations of elements (Z = 1 to 56), ions and the Periodic Table

The uses of radioactive Isotopes emitting alpha, beta or gamma radiation


Topic 3 Periodicity (Core IB Chemistry topic)

Summary of the Periodic Table - A basic introduction: Explanation and overview of Groups, Periods, Series etc. with links to more detailed notes on the Group 1 Alkali Metals, Group 7 Halogens, Group 0 Noble Gases and Transition Metals. (uses old group number notation)

Historical Introduction to the modern periodic table and the nuclear physics origin of elements

Electronic Structure of atoms -  s p d f orbitals - electronic basis of periodic table

Electron configurations of elements (Z = 1 to 56), ions and the Periodic Table

Spectroscopy, hydrogen spectrum, evidence of quantum levels, ionisation energy patterns

Survey of Period 3: sodium Na to argon Ar (3 pages)

Period 3 trends & explanations of physical properties

Period 3 trends in bonding, structure, oxidation state, formulae and reactions

Important trends down Groups

Revision notes on Inorganic redox reactions - section on electronegativity

Group 17 Halogens - Halogen displacement reaction and reactivity trend

Group 1/2 Alkali/Alkaline Earth Metals - Water reaction & hydroxides


Topic 4 Chemical Bonding and Structure (Core IB Chemistry topic)

Chemical bonding  (Core IB Chemistry topic)

INDEX of all my CHEMICAL BONDING notes

Why is knowledge of chemical bonding & structure so important?

Introduction to chemical bonding - why? how? and patterns

Ionic Bonding: compounds and properties

Covalent Bonding: small molecules & properties

Giant covalent structures and other big molecules

Metallic Bonding – structure and properties of metals

Electronegativity, bond polarity, type of chemical bonding

More on ionic structures and ionic bonding

(Working out electron configurations for atoms and ions)

More on covalent bonding - single, double & triple bond length & strength, dative bonds

Types of Crystal Structure and their relative physical properties

Shapes of molecules  (Core IB Chemistry topic)

Introduction - VSEPR theory - lots of inorganic molecule/ion examples

Some other molecules/ions of carbon, nitrogen, sulphur and chlorine

shapes and bond angles of organic molecules

Intermolecular forces - intermolecular bonding  (Core IB Chemistry topic)

Introduction to intermolecular forces - intermolecular bonding

Detailed comparative discussion of boiling points of 8 organic molecules

Boiling point plots for six organic homologous series, explaining trends and differences

Case studies of boiling points related to intermolecular forces for a variety of compounds

Evidence & theory for hydrogen bonding in covalent hydrides, importance in other molecules


Topic 5 Energetics-Thermochemistry   (Core IB Chemistry topic)

Basic notes of exothermic and endothermic reactions and calculation of enthalpy changes from 'simple' calorimetry experiments and resulting data

Basic notes of exothermic and endothermic reactions and calculation of enthalpy changes from 'simple' calorimetry experiments and resulting data

Enthalpy changes - thermochemistry - Calorimetry experiments - Enthalpies of reaction, formation, combustion and bond dissociation are explained with exemplar calculations

Thermochemistry - Hess's Law and Enthalpy Calculations - reaction, combustion, formation etc.

Bond Enthalpy Calculations

Experimental methods for determining enthalpy changes and treatment of results

Some enthalpy data patterns

The combustion of linear alkanes and linear aliphatic alcohols

Some patterns in Bond Enthalpies and Bond Length

Enthalpies of Neutralisation

Enthalpies of Hydrogenation of unsaturated hydrocarbons and evidence of aromatic ring structure in benzene

A set of structured practice Enthalpy Questions

Fully worked out ANSWERS to the ΔH enthalpy Q's above


Topic 6 Chemical Kinetics   (Core IB Chemistry topic)

  1. Notes for the basics of rates of reactions

  2. KINETICS - advanced rates of reactions revision notes: temperature effect and activation energy, homogeneous catalysts & heterogeneous catalyst, obtaining data


Topic 7 Equilibrium   (Core IB Chemistry topic)

Starter notes on reversible reactions and chemical equilibrium (includes introduction to Le Chatelier's Principle

Advanced Chemistry Equilibria Part 1. Dynamic molecular equilibrium and Le Chatelier's principle

Equilibria Part 2 Kc and Kp equilibrium expressions

Equilibria Part 3 equilibrium and industrial processes


Topic 8 Acids and Bases   (Core IB Chemistry topic)

Simple Introduction to Acid-Base Theory and Weak and Strong Acids

Equilibria:  Lewis and Bronsted-Lowry acid-base theories

Self-ionisation of water and pH scale

Strong acids - examples and pH calculations

Weak acids - examples & pH, Ka and pKa calculations

Strong bases - examples and pH calculations

Weak bases - examples and pH, Kb and pKb calculations

Acid-base indicator theory, pH curves and titrations

Volumetric titration procedures and calculations e.g. acid-alkali titrations (and diagrams of apparatus and descriptions of procedures) and calculations

Advanced level acid-base titration calculation questions (2 pages and worked out answers)


Topic 9 Redox processes - oxidation and reduction   (Core IB Chemistry topic)

Introduction to oxidation-reduction (redox) reactions

Revision notes on Inorganic redox reactions - Part 1 electronegativity, explaining oxidation and reduction reactions and oxidation state/oxidation number changes

Revision notes on Inorganic redox reactions - Part 2 analysing and constructing full redox equations from half-cell reactions

Electrochemistry - an introduction to electrolysis, theory, electrolysis cells, industrial electrolysis process links summary, experimental methods for electrolysis, electrode equations, simple cells/batteries, fuel cells etc.


Topic 10 Organic chemistry   (Core IB Chemistry topic)

INDEX of ALL revision notes on the chemistry of ALKANES and the petrochemical industry

INDEX of ALL revision notes on the chemistry ALKENES

INDEX of ALL revision notes on the chemistry of HALOGENOALKANES (haloalkanes)

INDEX of ALL revision notes on the chemistry of ALCOHOLS (and mention of ethers)

A summary of homologous series, functional group names and structure in Organic Chemistry

General test on type of Organic Molecule Recognition based on examples of structure and recognition of functional groups, including isomers, so the quiz is mainly on recognition of types of molecules and their structural features and classification

 Organic Chemistry ISOMERISM general definition (use sub-index at top of page)

 Organic Chemistry (1) STRUCTURAL ISOMERISM general definition (use sub-index at top of page)

 Organic Chemistry (1a) Chain isomerism (use sub-index at top of page)

 Organic Chemistry (1b) Positional isomerism (use sub-index at top of page)

 Organic Chemistry (1c) Functional group isomerism (use sub-index at top of page)

Revision notes on the structure & naming (nomenclature) of ALKANES (and cycloalkanes) notes, including nomenclature of isomers

Multiple choice Quiz on the structure and naming (nomenclature) of alkanes

Type in name Quiz on the structure & naming of ALKANES (and nomenclature of cycloalkanes)

Revision notes on the structure & naming (nomenclature) of ALKENES (and cycloalkanes) notes, including nomenclature of isomers

Multiple choice Quiz on the Structure and naming (nomenclature) of ALKENES

Type in name Quiz on the nomenclature of ALKENES

Revision notes on the structure and naming of HALOGENOALKANES (haloalkanes notes parts 1-3), including nomenclature of many isomers

Multiple choice Quiz on the structure and naming (nomenclature) of HALOGENOALKANES (haloalkanes)

Type in name Quiz on the nomenclature of HALOGENOALKANES (haloalkanes)

Revision notes on the structure and naming (nomenclature) of aliphatic ALCOHOLS (including classification into primary, secondary and tertiary alcohols) and isomers, does include ethers, epoxy-alkanes which may not be needed

Multiple choice Quiz on the structure and naming (nomenclature) of aliphatic ALCOHOLS and ethers

Type in name Quiz on the nomenclature of aliphatic ALCOHOLS and ethers

Revision notes on the Structure and Naming of Aldehydes and Ketones, including nomenclature of isomers

Multiple choice on the structure and naming (nomenclature) of Aldehydes and Ketones

Type in name Quiz on the nomenclature of Aldehydes and Ketones

Revision notes on the structure and naming of CARBOXYLIC ACIDS and DERIVATIVES, including nomenclature of isomers

Multiple choice Quiz on the Structure and naming of CARBOXYLIC ACIDS & DERIVATIVES

Type in name Quiz on the nomenclature of CARBOXYLIC ACIDS & DERIVATIVES

Matching pair Quiz on aldehydes, ketones, carboxylic acid and ester structure (drag and drop/printout version)

Combined matching pair Exercises on organic molecular structure

GCSE notes on Oil and useful products - The hydrocarbons from oil and their uses e.g. fuel combustion, fossil fuels and environmental problems, polymerisation, polymers etc.

 MECHANISM Introduction and terms used in organic chemistry (on the mechanism pages the type of reaction, basic reaction equations and conditions are quoted which may act as a suitable reference, also a reaction index)

 Mechanism of the free radical chlorination/bromination of alkanes to make halogenoalkanes

Alkanes and Petrochemical Industry INDEX

The Molecular Structure and Nomenclature of Alkanes

Fractional distillation of crude oil and uses of products

Modification of alkanes by cracking, isomerisation and reforming

Complete and incomplete combustion of alkanes and environmental pollution

Modification of hydrocarbon fuel mixtures and alternative fuels

Chlorination and bromination of alkanes, reaction mechanisms and uses of products


Topic 11 Measurements and data processing   (Core IB Chemistry topic)

Introduction to the interaction of electromagnetic radiation with matter

Introduction to mass spectrometry

Index of mass spectroscopy notes: mass spectrometry of organic compounds, examples explained

Index of infrared spectroscopy notes: infrared spectra analysis of organic compounds, examples

Nuclear magnetic resonance spectroscopy: 1H NMR spectra of organic compounds, examples

Simple NMR problem solving with % composition and infra-red absorption data


Additional Higher Level Topics 12 to 20  (IB Chemistry)

Topic 12 Atomic structure  (Additional higher level IB Chemistry topic)

Spectroscopy, hydrogen spectrum, evidence of quantum levels, ionisation energy patterns


Topic 13 The Periodic Table - Transition Metals  (Additional higher level IB Chemistry topic)

3d block and TRANSITION METALS Index and 20 linked pages


Topic 14 Chemical Bonding and Structure  (Additional higher level IB Chemistry topic)

Revision notes on shapes and bond angles of simple molecules (VSEPR), ions, transition metal complexes and a section on shape and bond angles in organic molecules


Topic 15 Energetics - Thermochemistry  (Additional higher level IB Chemistry topic)

Basic notes of exothermic and endothermic reactions and calculation of enthalpy changes from 'simple' calorimetry experiments and resulting data

GCSE Multiple choice quiz on Energy Changes in Chemical Reactions

Thermodynamics Part 1: Thermochemistry - Calorimetry experiments - Enthalpies of reaction, formation, combustion and bond dissociation are explained with exemplar calculations

A Level Thermodynamics Part 2 ΔH Enthalpies of ion hydration, solution, atomisation, lattice energy, electron affinity and the Born-Haber cycle

Thermodynamics Part 3 ΔS Entropy and ΔG Free Energy Changes

Kinetic versus thermodynamic stability - includes example of free energy-entropy feasibility calculation


Topic 16 Chemical Kinetics  (Additional higher level IB Chemistry topic)

KINETICS - advanced rates of reactions revision notes: temperature effect and activation energy, homogeneous catalysts & heterogeneous catalyst, obtaining data, rate expressions and orders of reaction, deducing orders of reaction

KINETICS - advanced rates of reactions revision notes: Selected case studies of kinetics and rate expressions and calculations, deriving the activation energy Ea from kinetics-rates data and Kinetic versus thermodynamic stability

Heterogeneous and homogeneous catalysis mechanisms

Obtaining rate data, interpreting data, deducing orders of reaction and rate expressions

The Arrhenius equation and calculating the activation energy Ea from kinetics–rates data

 Mechanism: Halogenoalkanes (haloalkanes/alkyl halides) Nucleophilic substitution by water/hydroxide ion [SN1 or SN2, hydrolysis to alcohol] and  extra notes on kinetics, rds, molecularity, activated complex etc.


Topic 17 Equilibrium  (Additional higher level IB Chemistry topic)

Dynamic molecular equilibrium and Le Chatelier's principle

How to write equilibrium expressions and the effect of temperature on the equilibrium constant K

How to write Kc equilibrium expressions, units and exemplar Kc calculations including esterification

How to write Kp expressions, units, partial pressures and exemplar Kp equilibrium calculations

Equilibrium and industrial processes

More on ΔG, Free energy changes, feasibility and applications

Calculating equilibrium constants from free energy change


Topic 18 Acids and Bases  (Additional higher level IB Chemistry topic)

Equilibria:  Lewis and Bronsted-Lowry acid-base theories

Equilibria: pH, weak-strong acid-base theory and Ka, kb and Kw equilibrium calculations

Equilibria: Salt hydrolysis, Acid-base titrations-indicators, pH curves and buffers

Appendices on Transition Metals: Appendix 1. Acidity of hexa-aqua ions

Structured Question worksheet on Acid-Base volumetric titration calculations (answers)


Topic 19 Oxidation and reduction  (Additional higher level IB Chemistry topic)

Equilibrium Part 7 Redox equilibria, half-cell electrode potentials, predicting feasibility of a reaction, electrolysis and electrochemical series

Redox equilibria, half-cell reactions and electrode potentials

Simple cells notation and construction

The hydrogen electrode and standard conditions

Half-cell potentials, Electrochemical Series and using Eθcell for reaction feasibility

More on ΔG, Free energy changes, feasibility and applications

Electrochemical cells ('batteries') and fuel cell systems

section 13. electrolysis calculations


Topic 20 Organic Chemistry  (Additional higher level IB Chemistry topic)

INDEX of ALL revision notes on the chemistry ALKENES

INDEX of ALL revision notes on the chemistry of HALOGENOALKANES (haloalkanes)

INDEX of ALL revision notes on the chemistry of AROMATIC COMPOUNDSgen

 Mechanism: Halogenoalkanes (haloalkanes/alkyl halides) Nucleophilic substitution by water/hydroxide ion [SN1 or SN2, hydrolysis to alcohol] and  extra notes on kinetics, rds, molecularity, activated complex etc.

 Mechanism: Halogenoalkanes (haloalkanes, alkyl halides) Nucleophilic substitution by cyanide ion to make a nitrile

 Mechanism: Halogenoalkanes (haloalkanes, alkyl halides) Nucleophilic substitution by ammonia to make a primary amine

Organic synthesis redox reactions - including reduction of nitriles (use top summary table index)

 Mechanism: Halogenoalkanes (haloalkanes, alkyl halides) Elimination of hydrogen bromide to give an alkene

 Organic Chemistry (2) STEREOISOMERISM general definition (use sub-index at top of page)

 Organic Chemistry E/Z (geometrical Isomerism) (use sub-index at top of page)

 Organic Chemistry R/S (optical Isomerism) (use sub-index at top of page)

Spotting optical isomers Q (hand written) (answers)


Topic 21 Measurement and data processing  (Additional higher level IB Chemistry topic)

INDEX and Introduction to the interaction of electromagnetic radiation with matter

Index of mass spectroscopy notes: mass spectrometry of organic compounds, examples explained

Index of infrared spectroscopy notes: infrared spectra analysis of organic compounds, examples

Nuclear magnetic resonance spectroscopy: 1H NMR spectra of organic compounds, examples


Options Standard Level/Higher Level: Core and higher level topic options

(just some selected links that might be of use - but nothing like the same cover of the 20 'non-option' topics)


OPTION A Materials (IB Chemistry option topics)

Core topics (IB Chemistry option topics)

Heterogeneous and homogeneous catalysis mechanisms

NANOCHEMISTRY index - nanoscience nanoparticles fullerenes carbon nanotubes

Higher level topics (IB Chemistry option topics)

The manufacture, molecular structure, properties and uses of polyesters

Amides chemistry - a mention of polyamides

The structure, properties and uses of polyesters and polyamides involving aromatic monomers

The chemistry of amides including Nylon formation, structure, properties and uses

Stereoregular polymers -  isotactic/atactic/syndiotactic poly(propene) - use of Ziegler-Natta catalysts

3d block Transition Metals - Complexes & ligands

Solubility product Ksp & common ion effect


OPTION B Biochemistry (IB Chemistry option topics)

Core topics (IB Chemistry option topics)

Photosynthesis, importance explained, limiting factors affecting rate

Respiration - aerobic and anaerobic in plants (and animals)

Amino acids - molecular structure, preparation and reactions - two functional group

Protein-enzyme structure, function and inhibition

Protein analysis & synthesis AND combinatorial chemistry and autosynthesis

Natural esters - triglyceride fats and oils, manufacture of margarine and biodiesel

Higher level topics (IB Chemistry option topics)

Enzyme kinetics

Other organic stereochemistry including amino acids-proteins-polypeptides-enzymes (including enzyme inhibition)

Buffers - definition, formulation and action

Buffer calculations

Case studies of buffer function

Amine bases and the hydrogen bonding in DNA and RNA

The uv-visible absorption spectra of the photopigments in the human eye

The uv-visible absorption spectrum of haemoglobin (porphyrin pigment)

The uv-visible absorption spectrum of melanin pigments


OPTION C Energy (IB Chemistry option topics)

Core topics (IB Chemistry option topics)

Modification of hydrocarbon fuel mixtures, alternative fuels and global warming

The laboratory synthesis and manufacture of alcohols

Biofuels and alternative fuels, hydrogen, biogas, biodiesel

Fractional distillation of crude oil and uses of products

Modification of alkanes by cracking, isomerisation and reforming

Nuclear Fission Reactions, nuclear power energy resource

Nuclear fusion reactions and the formation of 'heavy elements'

Photosynthesis, importance explained, limiting factors affecting rate

Higher level topics (IB Chemistry option topics)

Simple cells notation and construction

The hydrogen electrode and standard conditions

Half-cell potentials, Electrochemical Series and using Eθcell for reaction feasibility

Electrochemical cells ('batteries') and fuel cell systems

Exemplar Questions, Appendix 1. The Nernst Equation, Appendix 2 Free Energy, Cell Emf

Half-life of a radioisotope, implications!, uses of decay data , half-life values, radiocarbon dating, dating rocks

Alpha, beta & gamma radiation, properties, dangers of radioactive emissions

The uv-visible absorption spectra of alkenes

The uv-visible absorption spectra of selected aromatic compounds - arenes


OPTION D Medicinal chemistry (IB Chemistry option topics)

Core topics (IB Chemistry option topics)

preparation of aspirin: Preparation and reactions of acid/acyl anhydrides, including making aspirin

Buffers - definition, formulation and action

Buffer calculations

Case studies of buffer function

Half-life of a radioisotope, implications!, uses of decay data , half-life values, radiocarbon dating, dating rocks

Higher level topics (IB Chemistry option topics)

What happens to the nucleus in radioactive decay?, nuclear equations, production of radioisotopes

Index of all spectroscopy pages and introduction

Introduction to mass spectrometry

Index of mass spectroscopy notes - examples of mass spectrometry of organic compounds

Index of infrared spectroscopy notes - analysis of infrared spectra of organic compounds

Index of nuclear magnetic resonance spectroscopy 1H NMR spectra of organic compounds

Index of emission and absorption spectroscopy including colorimetry and flame photometry

HL only transition elements - mention of cis-platin

HL only  Organic Chemistry R/S Optical Isomerism (use sub-index at top of page)

HL only  Organic stereochemistry including section 2b.4 on Thalidomide

HL only  chiral auxiliaries and  combinational chemistry


PAST PAPERS practice paper links  (IB Chemistry)

Higher Papers https://www.freeexampapers.com/past_papers.php?l=Past_Papers%2FIB%2FChemistry%2FHigher/

Standard papers https://www.freeexampapers.com/past_papers.php?l=Past_Papers%2FIB%2FChemistry%2FStandard/


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