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Advanced Level Organic Chemistry: HALOGENOALKANES - index of revision pages

Part 3. The chemistry of HALOGENOALKANES (haloalkanes, old name alkyl halides)

Doc Brown's Chemistry Advanced Level Pre-University Chemistry Revision Study Notes for UK KS5 A/AS GCE IB advanced level organic chemistry students US K12 grade 11 grade 12 organic chemistry

INDEX of halogenoalkanes revision notes

All Advanced A Level Organic Chemistry Notes

Index of basic Oil and Organic Chemistry Revision Notes

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Halogenoalkanes (haloalkanes) INDEX of revision notes

Abbreviations used: mpt = melting point and bpt = boiling point (oC or K units will be quoted)

3.1 Molecular Structure and Nomenclature of Halogenoalkanes (haloalkanes)

(Also includes an introduction on how to write and display halogenoalkane formulae including isomers)

Multiple choice test on naming halogenoalkanes (haloalkanes)

Type in name test on halogenoalkanes (haloalkanes)

To doc b! Do mixed naming quiz 3rd, and 4th version by adding other structure/reaction Qs from a 3rd data base?

3.2 Laboratory synthesis & industrial manufacture of halogenoalkanes (haloalkanes) from alcohols, alkanes, alkenes

3.3 Reactivity trends of halogenoalkanes - introduction to their nucleophilic substitution reactions, the substitution reaction between halogenoalkanes (haloalkanes) & water, experiments with silver nitrate solution

3.4 The substitution reaction of halogenoalkanes (haloalkanes) with sodium/potassium hydroxide to give alcohols

3.5 The nucleophilic substitution reaction between halogenoalkanes (haloalkanes) and potassium cyanide and hydrolysis of nitriles to carboxylic acids

3.6 The substitution reaction between halogenoalkanes (haloalkanes) and ammonia and amines forming primary, secondary and tertiary amines

3.7 The elimination reactions of halogenoalkanes (haloalkanes) with potassium hydroxide to give alkenes

3.8 The physical properties, hazards and uses of halogenoalkanes (haloalkanes)

3.9 The chemistry of ozone depletion and how this environmental problem was solved


Halogenoalkanes (haloalkanes) reaction mechanisms

The following notes have basic reaction conditions, reagents and general equations as well as detailed notes on the mechanisms indicated (overlap because they were written before above sections 3.2 to 3.7 were compiled)

Nucleophilic substitution by water/hydroxide ion [SN1 or SN2 mechanisms, hydrolysis to give alcohols]

with extra notes on kinetics, rds, molecularity, rate expression, activated complex etc.

Nucleophilic substitution by cyanide ion to give a nitrile [SN1 or SN2 mechanisms]

Nucleophilic substitution by ammonia/primary amine to give primary/secondary amines etc. [SN1 or SN2]

Elimination of hydrogen bromide to form alkenes [E1 and E2 mechanisms]

Free radical chlorination/bromination of haloalkanes to give halogenoalkanes - mechanism

Alkylation to give alkyl-aromatic hydrocarbons like methylbenzene [Friedel-Crafts reaction mechanism]


See also

 All Advanced A Level pre-university Organic Chemistry Notes

 Index of basic Oil and Organic Chemistry Revision Notes

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Doc Brown's Advanced Level Chemistry Revision Notes

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